Combustion inside a cylinder is not an immediate release of energy. It is spread out over mostly the power stroke and partly over the compression stroke of the piston. Rather than a single explosion , it burns as the piston moves down continuously releasing energy while the piston moves down.
When detonation occurs, the energy release is much more violent and immediate. A good analogy is if you were to push Car A with Car B. Lets say you butt Car B up to Car A then using 100 lbs of force push car A for 20 seconds. You've essentially put 2000 lbs of force into moving car A. Now lets imagine you put all 2000 lbs of force into car A into a single second. You'll be replacing some bumpers very shortly.
While the process of detonation is much more complicated, the end result is similar. Detonation releases a lot of energy in a very short period of time, which could ultimately lead to engine damage.
The cause of detonation is pressure. Heat is a contributing factor, but pressure is the primary trigger. The rate of burn of a fuel is not relevant as the process of detonation is not the same.
"Nitromethane is burned as a fuel in drag racing autos, but also can be made to detonate, a special kind of burning in which the material undergoes a much faster and far more violent type of chemical transformation. With its single nitrogen dioxide (NO2) group, it is a simple representative version of explosives with more NO2 groups."
The above is an exerpt from an article about a recent discovery about detonation. Additionally, it states:
"Though it is an optically transparent, electrically insulating material, it undergoes a shocking transformation: It turns into an optically reflecting, nearly metallic state for a short time behind the detonation shock wave front.
But further behind the wave front, the material returns to being optically transparent and electrically insulating."
Source:
http://www.sciencedaily.com/re...2.htm
The results of detonation and much of the conditions under which it occurs are known, but the process is still not fully understood.
However, the rate of burn a fuel experiences is not necessarily a reflection of it's propensiy to detonate. I've seen no scientific data to say otherwise and this article clearly shows there is a very different process going on that doesn't occur during normal combustion.
As for what knock isn't, it is not the pressure and resistance placed on a piston still moving up during the compression cycle if combustion starts before top dead center. All modern motors advance timing (usually between 10-20 degrees BTDC for each piston. This is to compensate for the fact that during normal combustion, it takes time for the flame kernel to grow to a size where it is releasing energy in a sufficient amount to be efficient and perhaps usable. Essentially, a small flame in the combustion chamber can not push down very hard on the piston so starting the combustion at TDC would mean that for part of the power stroke, the amount of force pushing down on the piston would be quite small. So the idea behind advanced timing is to grow the flame size prior to the power stroke so that it provides the most energy during the power stroke.
The problem is that detonation can occur even after combustion starts. Basically, as the piston moves up, there is a certain rate of compression going on. However, as fuel starts burning during compression, it expands the gasses due to the increase in heat, causing a bigger increase in pressure than the compression the piston provides by itself. So too much timing advance can be a bad thing. To help remedy some of this, a higher octane fuel can allow for some additional timing advance by allowing a higher pressure threshold before detonation is experienced.
In the case of the VQ, you have a high compression motor designed and tuned to run on higher octane fuel. Since the compression is static, the only way to use lower octane fuel is to reduce the timing advance. What happens here is that you get a less than ideal flame front as the power stroke begins and less peak pressure. The latter is significantly important in a high compression motor as the biggest benefit of higher compression is that the expansion ratio on the power stroke is greater. The higher expansion ratio allows for more of the heat and pressure to be converted into mechanical energy rather than being dumped out of the exhaust as pressure and heat and being transferred into the cooling system as heat. Starting with a lower peak cylinder pressure means there is less energy to be converted into mechanical energy.
Backing the timing can allow the motor to run safely on lower octane fuel, but it degrades the power output and efficiency. How much can vary quite a bit. Perhaps the best thing you can do is try both and see if the efficiency and power loss is outweighed by the cost of fuel. The knock sensor should pick up even the lightest events of detonation and keep timing retarded enough to prevent any engine failures.
Like some other higher performance vehicles, the VQ may on a continual basis, attempt to keep the vehicle running on the threshold of knock. This is suggested by the report by a magazine that put 100 octane fuel in a Z in an early test. HP did go up slightly. It's likely because the ecu advanced the timing until knock was heard and then ran timing at or just below that level. I can't recall which cars, but there are some cars that do this and the manufacturers were very vocal about it. I expect in an effort to continually increase performance and efficiency, and with continually increasing engine control technology, we will see this type of technology in more and more cars.