The wear could be caused by a couple things. The outer edge of the front tires generally wears fastest.. but not in one day.
That sounds odd, or you spent an hour or so coming in hot from the freeway... hitting the cloverleaf righthander at 60+mph
After one day, you shouldn't have excessive abnormal shoulder wear, from regular street use.
Tire pressure over time can be indexed/recorded (also you can get crazy and measure tire temp... money cures everything!)....... and you can masterfully dial in the ideal pressures within a given range of outside temperature and weather variables. Hot/rain/snow conditions all require different tires.
If the vibration was there before, and it shakes still, don't rule out a bent wheel as the culprit. You say it shakes every now & then.. perhaps the nylon cap ply in the tire is not at ideal operating temp at the time you feel the shake, or the balance performed was not optimized.
As far as where to go for alignment... I don't live there, but you could ask your dad or your friends and find out who they use.