It's usually not a smart idea just to pump "old" refrigerant back into a system. It picks up alot of crap over time, and the oil breaks down(just like your engine oil).
They might cut you a deal if you let them reclaim your refrigerant, especially if its R12, since they do get money by selling that to a place that will process the impurities out and resell it.
BTW - I worked on residential and commercial A/C for a summer, and you don't want to know how many times refrigerant gets vented, even if you take all the steps to try to reclaim it. Heck, where do you think all that R22 goes when a 300 ton(i.e. provides the cooling capacity of 300 tons of ice melting in 1 hour, in other words - lots) V8 commercial compressor sucks in liquid refrigerant then blows out a hole in the side of the block?!?! I seem to recall just the charge for refrigerant on that badboy being somewhere upwards of $600-700(a buncha 25lb cannisters - we called 'em green weenies since they were green and vaguely sausage shaped

).
Ahhh - the A/C job, good times, good times...