The flanges are different; the rb20 is a 14 bolt, the 25 is 13 (or 15, cant remember). Plus the ports for the 25 are WAY larger than the 20. You might be able to cut and weld the rb20 flange onto the rb25 manifold but the symmetry is different.
EDIT:
Here
s a 20 head with a 25 gasket:
