There is plenty of help on the forum for this modification. A search will bring these up.
Also, you can check out
http://sr20.hybrids.jp/install....html
The calipers will have 4 pistons in them if they are the front brakes. The thing to pay attention to is the brake lines and the width of the rotor it takes. You need to get are brake lines that will mate up with the S13 hardline and the Z32 caliper.On the subject of the rotor width, you said you got them off a 1990 Z32 TT. This would make the rotor width 30mm. All dimensions for the rotor are: 280mm x 30mm
Get the lines, pads, and rotors and you should be all set. Use those instructions above and I think you'll do fine.