First I'd like to ask why you would want to run Octane booster.
Secondly does your car need it for any certain reason? Forced induction, nitrous, track day abuse?
Most "octane" boosters you buy at Autozone, PepBoys etc are the s*** marketing junk that won't actually give you the advantages of raising your octane properly. They may raise the specific octane, but as mentioned earlier they do it by adding chemicals that cause other issues.
If you do actually need higher octane fuel because you're going to be racing, or you want to turn up the boost, or run a bit more nitrous. First off make sure your tune is set up for it. Then you have two choices, run unleaded race gas of a higher octane than what you find at the pump or run an actual octane booster like the Torco Additive.
http://torcoracefuel.net/pro-accelerator.html
We use it on a number of our customers race vehicles and also a number of other shops in the area run it when they want the added protection on their pump gas cars. It runs about $21+tax for a bottle that is good for five or ten gallons depending on what octane you need. Far less than having to buy race gas currently. It's also very well respected in the industry and a number of the chemical geeks that have reviewed it say it actually does what they claim, and it does it safely.
The other way to go, and requires the proper tune also is water or meth injection. Once again, it depends on what you're needing it for.