+1 for checking out the Z specific forums. Those guys have been modding the Z32 since there has been a Z32.
Getting the 100k service taken care of is the best advice for where to start. Once she's up to speck, you're going to be looking at some serious cash if you're serious about 450-500whp.
I suggest maxing out the stock turbo's first, which is about 15-16 psi if I remember correctly. In order to do this, you'll need a new ECU tune, and new injectors to match your tune. When upgrading your ecu and injectors, they are usually purchased as a matched set. Meaning the ECU tune will be for a factory mass airflow sensor and a set of 550cc injectors for example. Think about your end goal when shopping for an ECU tune. Get injectors that will be big enough to reach 450 whp.
If you use the calculator
HERE, you'll see that in order to achieve 500whp, you'll want at least a set of 550cc fuel injectors like I suggested above.
The guys in the Z32 forum will be able to point you in the right direction for sources to use for parts and whatnot. I'm only familiar with Jim Wolf Technology where the Z is concerned.
The internals of the VG30 will reach 500whp without requiring replacement. The big expense will be upgrading the turbo's and associated parts that go with, like the FMIC and exhaust etc.
The Z32 is a great car even in factory trim. Best of luck on your build!
Welcome to Nico!
WD