The problems are 2 fold" cold cylinders [bore]/heads which tend to allow gasoline vapors to condense and to quickly light off the precats and cats.
Extra unburned gasoline is burned [reacted] in cats..... too much and you can flood the cats lowering their temperature where the reaction stops.
Rich conditions are stepped down and are limited to 90 seconds by which the cats begin to come on line and reduce HC to acceptable levels. On newer engines with wideband O2, the warm up idle is controlled to 14.7AF as soon as a stable rpm can be maintained after the 30-90 seconds.
On older [heated narrow band] O2 sensors the AF ratio is just preprogrammed and O2 are not consulted until the O2 starts switching steadily, usually 3-5 minutes.
http://society.kisti.re.kr/~Ek...4.pdf
Now if you are really interested:http://vehicle.me.berkeley.edu...s.pdf