All 3 belts are serpentine belts. A serpentine belt is just a type of belt - it's flat with multiple grooves on the inside, and can be routed around a pulley in either direction. As opposed to an older V belt which is just wedge / V shaped, and cannot be routed backwards around a pulley, and really isn't used on modern cars anymore. Some cars like our 240's use multiple serp belts, other cars use one long serp belt routed to run everything. "Serpentine" has no correlation to what accessory it runs.
Now that you know all 3 are serp belts, I'm sure you can locate which belt is which using the trusty service manual which I'm sure you've downloaded and been reading

It's pretty easy. The AC belt is connected to the ac compressor. The alt belt is connected to the alt. The PS belt runs to the PS pump. One of them loops around the water pump pulley. It's all in the manual
A loose belt can cause problems with it's associated accessory, and cause noises, but so can a bad pulley - and may not necessarily be the cause of the starting problem you're experiencing. Clicky sound sounds more like a starter relay issue
