I went back an got out the calculator. The Q45 engine should have bottom dead center volume per cylinder of 623 cc and a TDC volume of 61 cc (difference of 562 cc's per cyclinder and a ratio of 10.2:1) In a pressure test situation I forgot about the affect of temperature on pressure. While the density of the gas will increase inverse linearly with volume, the pressure won't. Pressure will increase along a slight exponential when compressed rapidly due to a rise in temp.
Q45tech wrote:Worse yet what brand of gasoline will NOT KNOCK with a 11.5 CR even a 11.0 would be a problem..
This might suggest my theory that compression tests can be artifically increased by piston deposits could be wrong.
The "deposit increased CR ratio and knocking problem" consideration might suggest that even thin despoits on the head or pistons could lead to drivability problems - except that these problems would only show up at or near WOT.
Isn't detonation (spontaneous combustion without a spark) a function of high density and temperature. Different fuels have a curve on a graph (temp verses density) where above the curve an air fuel mixture will spontaneously burn. The Q's engine is designed so that with 93 octane fuel the conditons will never exist. Even low octane fuel will idle fine in a Q45 since the amount of air and fuel admitted is so small that the density level won't get very high.
[Assume 675 rpm idle requires 10HP - about 4 gr /sec of air - this becomes .09 gr / cylinder / cycle = 1/7th normal air pressure meaning cylinder pressure before ignition is never more than 20 psi]
It's only as the cylinder pressure before ignition increases to high levels ( 150+ PSI?) that the engine approaches the detonation threshold for lower octane gas - thus in Denver 93 doesn't really need to be true 93 since the CPbi won't approachs the detonation threshold for lower octane gas.
Going out on limb; I might suggest that cylinder despoits if excessive (more than a few CC's per cylinder) might actually be causing detonation at WOT, if the detonation occurs only a couple degress before intended igntion the effect won't rattle the block very much and the only tangible effect is a loss in power - how one would test this theory, I have no idea.