You could have a leak from your water pump, a hose, a thermostat housing, radiator, coolant reservoir, or heater hoses. Try and isolate where the leak is coming from.
For the smoke, I would definitely have a compression test done. That will tell you if you have a bad head gasket or anything else.
Definitely have the thermostat and the water pump replaced during the 120k. Make sure they replace idlers, tensioner, cam and crank seals, etc. Do it right and do it once
The squeal could be from loose accessory belts on the front of your engine. They will be removed for the 120k, and they should be re-tensioned properly after that. If they are cracked up, might as well replace them as well.
Are you sure you aren't leaking fuel also? There shouldn't be a fuel smell in your coolant, I don't really know how that would happen unless you have a fuel leak dripping into that pan also. Is there maybe fuel residue left in the pan from when it was used another time? Do you ever smell fuel inside the car when you are driving or when you turn the heat/ac on?