"The State of California banned the use of MTBE in gasoline starting in December 2002 with a 2 year phaseout period: 0.3 v% max in 2003, 0.15 v% in 2004, and 0.05 v% afterwards. This caused a political chain reaction and other states have passed or are in the process of passing similar legislation.
What are the implications? We lose about 11% of volume, representing the percentage of MTBE in gasoline. We also lose the contaminant dilution effect (10-15% for S, 6 to 8% for aromatics, and 0.2 to 0.3% for benzene). MTBE is also a high octane component (118RON), and its elimination reduces the blend octane by 2 to 3 octane numbers. Finally it raises the T50% by 20 degrees.
The situation can be helped through the use of more expensive alternatives:
1. Use of Ethanol (~ 6 v%) provides the oxygenate content mandated by EPA RFG-2, regains 6% of volume and associated dilution benefits, and gains some octane
2. Use of Alkylate regains some of the volume and associated dilution benefits, helps compensate for Ethanol RVP problems, and gains some octane
3. Gain octane by using higher octane reformate and FCC gasoline by increasing process units severity "
http://www.r-t-o-l.com/modules...id=98
http://www.nescaum.org/committ...i.pdf
