Put alot of time into the prep work.
I started out with a 150 grit paper to sand the car on an orbital sander. Than after that I went up to a 240 grit with the orbital and sanding block as well.
For all the tight spaces where you cant get your block into just use your fingers, it'll be fine.
I'm currently working on painting my car and i've spent about a good 2 weeks working on the sanding and making sure I have everything done.
The door jambs and tight spots like those will be very tricky to get to unless you take off the door, than it'll make it 100x easier.
Try to remove as much as possible from the car and than get envelopes and store all the bolts, nuts, plastic holders and label it.
Wash your car for sure or else you'll be like me and have to do double the work. If you get to a spot where you accidently hit the bare metal don't even sweat it just get some cheap old primer from walmart or any autoparts store and primer it right away so you don't accumulate corrosion.
I'm getting all my stuff from here. There's been all kinds of people who use this for classic cars and they have some sick paint jobs that are no joke.
http://www.southernpolyurethanes.com
If you search on google too you can find a forum from people who have used the products.
The way I'm doing mine is getting epoxy primer which basically takes the place of ethching primer. Then I'm going to lay the 2K High build primer over that after I've filled in the small dings and minor dents on my body panels.
GL with painting, but remember, it's all in the prep work, the better the prep work, the better your results.