Start with the basics. (Replace if needed). All fluids&filters, air filter, belts, gaskets, hoses, plug wires, pressure testing is probably necessary. After sitting for five years, there's bound to be some small problems arising soon.
Another thing I would pick up is a Haynes manual, they're pretty inexpensive and will be your best friend when working on your Z.
Here's where I bought mine:
http://www.amazon.com/Nissan-1984-1989- ... 1850105634