It will bolt on. The engine you end up with lacks (think?) the crank girdle of a true CA18DET, and the rods won't be quite as strong. You'll need to use the harness and ECU from the DE engine if you're not going standalone. If you have the engines readily available and the time to do it, its an option. The way I see it, in 4-5 years this will be the norm as we'll have run through all the reasonably priced (and/or worthwhile) JDM imports.
There was someone on here that was going turbo on a CA18DE, they might have more specifics on the DE's head. I believe
http://www.club-s12.org/ has a few discussions on the conversion you're suggesting as well.
What technical things about the head are you referring to?