I don't think I'm aware of a cooling system that isn't pressurized...
220 is at the upper end of what I would call "normal". Lots of cars run cooler than that (195-205ish), but I know GM likes to run things hot (up in the 220 range).
I also wonder if your coolant was replaced with the correct mixture, or if its 100% glycol (instead of a mixture).
Typically you can run more water (like say 65% water to 35% coolant) and it will transfer heat better... and you should be able to do that seeing as how you're not worried about temperatures getting down to -40
